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Assessment of Heavy Metal Pollution of the Snow Cover of the Severodvinsk Industrial District (NW Russia) Полный текст
2022
Yakovlev, Evgeny | Druzhinina, Anna | Zykova, Elena | Zykov, Sergey | Ivanchenko, Nikolay
Severodvinsk city is the largest industrial center for the construction and repair of naval vessels in the NW Russia. The purpose of the presented study was to identify the main sources of pollution of the Severodvinsk industrial region and assess the ecological situation based on analysis of toxic metals in water and snow. Heavy metals content in water, melt snow filtrate and solid residue was measured using ICP-MS. On the urban area, there were high concentrations of Fe (up to 2843 MPC) in soluble form of snow, Al (up to 4680 MPC), Fe (up to 2807 MPC), Ni (up to 66.5 MPC), Pb (up to 44.7 MPC), Cd (up to 43.3 MPC), Cr (up to 43.2 MPC), Mn (up to 13.3 MPC), Co (up to 7.3 MPC), and As (up to 3.4 MPC) in insoluble form of snow, Fe (up to 56213 MPC) in water from wells. There were high values of mineralization (598 mg/L) and low pH values (to 5.21) in sites most susceptible to anthropogenic pollution. Statistical analysis showed that most of the metals in snow cover were linked with each other by strong correlation (r>0.9). Calculation of toxicological indices HMEI, HMPI, HMTL, HI and CR showed extremely high and dangerous for public health level of heavy metal pollution in the Severodvinsk industrial district. Studied radiation parameters of water from wells were within acceptable limits. Results obtained indicate the need to change the type of fuel in thermal power plant and reduce toxic emissions from the shipbuilding enterprises.
Показать больше [+] Меньше [-]Microplastics Abundance, Characteristics, and Risk in Badagry Lagoon in Lagos State, Nigeria Полный текст
2022
Yahaya, Tajudeen | Abdulazeez, Abdulmalik | Oladele, Esther | Williams, Evelyn | Obadiah, Caleb | Umar, Ja’afar | Salisu, Naziru
Microplastics are widely used to manufacture diverse products such as textiles, skin care products, and household products such as detergents and soaps. However, microplastic pollution and its potential health risks are raising concerns worldwide. This study characterized and determined the safety of microplastics in water and sediments obtained from three locations, namely Ibeshe, Amuwo Odofin, and Ojo along Badagry lagoon, Lagos, Nigeria. The samples of the lagoon's surface water and sediments were treated and analyzed for the abundance of microplastics, as well as their shapes, sizes, and types of polymers. The risk index of the polymers in the microplastics was also estimated. Microplastics were found to be more abundant (p ≤ 0.05) in the sediments (283–315 particles/kg) than in the surface water (108–199 particles/L). In both the water and sediments at all the locations, the dominant shapes were fibers (52%–90%), followed by fragments (3%–32%) and films (1%–25%). In order of significance, the microplastic size range of 0-100µm and 100-500µm dominated the surface water, while the size range of 1000-5000µm and 500-1000µm dominated the sediments at all the locations. The dominant polymers in both the water and sediments at all the locations were polyethylene, polypropylene, and polyamide, while the least was polystyrene. In both the water and sediments at all the locations, the dominant risk score among the polymers is III (moderate risk). The results obtained suggest that microplastic pollution poses environmental and health risks to the lagoon, aquatic organisms, and humans. As such, the lagoon required microplastic remediation and control.
Показать больше [+] Меньше [-]Heavy Metal Pollution in Soils and Vegetables from Suburban Regions of Nairobi, Kenya and their Community Health Implications Полный текст
2022
Nyika, Joan | Dinka, Megersa
This study aimed at quantifying the heavy metal levels in soils and vegetables sampled from five suburban regions of Nairobi, Kenya. Using inductively coupled plasma- mass spectrometry (ICP-MS) the metals were quantified from the samples. The assayed heavy metals including Cd, Cr, Co. Cu, Fe, Hg, Mn, Ni, Pb, Zn and the metalloid arsenic were elevated beyond the reference values in both soils and vegetables. High pollutant levels in soils were affiliated to use of industrial and domestic wastewater for irrigation, application of heavy metal containing agrochemicals and geogenic sources of the pollutants. In collard leaves, the uptake of contaminated water via the roots and subsequent accumulation in the leaves was attributable to the observed results. The total hazard quotient (THQ) and hazard index (HI) as a result of arsenic and Hg was >1 in all sampled sites and >10, respectively for both indices and heavy metals. Similarly, the cancer risk (CR) and target cancer risk (TCR) from consumption of collard was greater than the recommended levels of 10-6 and 10-4, respectively with exception of Pb. The indices were indicative of negative non-carcinogenic and carcinogenic effects of consuming the vegetables to the community of the study area. The results of the study, though preliminary, suggest the need to safeguard the health of communities in the study area to ensure that they do not consume heavy metal contaminated vegetables due to the established health effects of such pollutants.
Показать больше [+] Меньше [-]Monitoring Nature’s Kidneys with the aid of Macrobenthic Assessment: A case study in the city Wetlands of Guwahati, India Полный текст
2022
Talukdar, Debashish | Basumatari, Devajit | Rahman, Shamim
Aquatic environments, including wetlands, are one of the most threatened ecosystems worldwide. Considering their ecological importance, wetlands are rightly appraised as ‘natural kidneys’. In this current study, the city wetlands of Guwahati were viewed for the first time through the angle of lesser-explored bottom dwellers. Guwahati, a rapidly expanding metropolis, is the gateway to northeast India, part of an Indian biodiversity hot-spot region. This case study comprised the bridge between abiotic and biotic factors, thus directing the pave for characterization of wetlands through benthos analysis. The study, covering seasons, viz. winter, premonsoon and monsoon, revealed 15 definite taxa belonging to 10 orders. The dominance of Chironomidae and Culicidae in certain wetlands indicated high tolerance of Dipterans in a wide range of aquatic environments, including polluted water bodies. Similarly, the presence of Trichopterans, only in the wetland located distant from the mainland city, marked that with less anthropogenic impacts. The Shannon indices for benthos were in the range from 0.17 to 0.97. Density was found to have a significant positive correlation with dissolved oxygen (r = 0.567) and a negative correlation with free carbon dioxide (r = -0.377). In contrast to significant site- wise variation in density, there was no significant difference in benthic diversity across the sites and no significant seasonal variation of benthic density and diversity from the statistical point of view.
Показать больше [+] Меньше [-]Biosorption Potential of Saraca asoca Bark Powder for Removal of Cr (VI) Ions from Aqueous Solution Полный текст
2022
Lall, Anurag Samson | Pandey, Avinash Kumar | Mani, Jyoti Vandana
Saraca asoca bark has long been used in traditional Indian medicine. Considering its low cost and non-toxic nature, it can find application as a biosorbent. This article explores the application of Saraca asoca bark powder (SABP) for biosorption of hexavalent chromium. Various analytical techniques including Field emission scanning electron microscope (FESEM) attached with energy dispersive spectrometer (EDS), Fourier transform infrared spectroscopy (FTIR) and point of zero charge (pHpzc) were adopted in order to identify the physico-chemical features of SABP. Factors such as pH (2-8), contact time (for 3 hours), initial Cr (VI) concentration (10 – 250 mg/l) and temperature (15 - 35°C) were examined for their influence on Cr (VI) biosorption via batch studies. Biosorption data clearly followed Redlich-Peterson isotherm model as compared to Langmuir and Freundlich models. The Langmuir monolayer adsorption capacities (Qm) at 15, 25 and 35°C were 123.4, 125.0 and 175.4 mg/g respectively. Biosorption followed pseudo-second-order kinetics and the mechanism of diffusion was governed by both surface sorption and pore diffusion as demonstrated by the plot for Intraparticle diffusion model and the pore diffusion coefficient (Dp~10-9 cm2/s). The nature of biosorption was found to be spontaneous and endothermic as reflected through various thermodynamic parameters such as the free energy change (ΔG = -3.0 to -3.7 kJ/mol), entropy change (ΔS = 37.8 J/K/mol) and enthalpy change (ΔH = 7.9 kJ/mol). The study recommends that SABP may be utilized as a potential biosorbent for Cr(VI) ions.
Показать больше [+] Меньше [-]Temporal Analysis and Forecast of Surface Air Temperature: case study in Colombia Полный текст
2022
Romero Leiton, Jhoana Patricia | Torres, Diego | Romero, Manuel
In this work, we study the short-term dynamics of the Surface Air Temperature (SAT) using data obtained from a meteorological station in Bogotá from 2009 to 2019 and using time series. The data that we used correspond to the monthly mean of the historical registers of SAT and three pollutants. A descriptive analysis of the data follows. Then, some predictions are obtained from two different approaches: (i) a univariate analysis of SAT through a SARIMA model, which shows a good fit; and (ii) a multivariate analysis of SAT and pollutants using a SVAR model. Suitable transformations were first applied on the original dataset to work with stationary time series. Subsequently, A SARIMA model and a VAR(2) with its associated SVAR model are estimated. Furthermore, we obtain one-year forecasts for the logarithm of SAT in both models. Our forecasts simulate the natural fluctuation of SAT, presenting peaks and valleys in months when SAT is high and low, respectively. The SVAR model allows us to identify certain shocks that affect the instant relationships among variables. These relations were studied by the impulse-response function and the VAR model variance decomposition. Although the statistical methods used in this study are classical, they continue being widely used in the environmental field, presenting god fits, and the results obtained in this study are consistent with environmental theories.
Показать больше [+] Меньше [-]Daily and Seasonal Variation of Aerosol Optical Depth and Angstrom Exponent over Ethiopia using MODIS Data Полный текст
2022
Eshet, Asmarech | Raju, Jaya Prakash
Aerosols are tiny particles (liquid or solid) suspended in the atmosphere. They play a significant rolein climate dynamics directly or indirectly. Aerosol Optical Depth (AOD) and Angstrom Exponent(AE) are significant parameters to study the concentration and size or type of aerosol over an area,respectively. In this article, we utilized three years of AOD and AE parameters derived from moderateresolution imaging spectroradiometer (MODIS) satellite during the period January, 2013 to December,2015 over Ethiopia. In order to study the spatiotemporal pattern of aerosols, we choose three areas(Debretabour, Gojjam and Addis Ababa) over Ethiopian highlands, which are representative of nonindustrial, agricultural and industrial areas respectively. Further we compare continental aerosols withmarine aerosols from Djibouti. Our results clearly depicts the aerosol distribution over Ethiopia ishighly variable spatially and temporally. The results indicates that the urban and biomass aerosols aredominate over Addis Ababa, and Gojjam respectively, whereas dust and biomass aerosols are presentover Debretabour, while Djibouti is loaded by sea spray aerosols. The seasonal variability of AOD isfound to be maximum during the kiremt (summer) and minimum during bega (winter) over all areas(continental and marine).
Показать больше [+] Меньше [-]Correlation Study of Meteorological Parameters and Criteria Air Pollutants in Jiangsu Province, China Полный текст
2022
Johnson, Anbu Clemensis
Air pollution is a global issue and meteorological factors play an important role in its transportationand regional concentration. The current research is aimed to analyse the variations in meteorologicalparameters in a seasonal and geographical location context in the Jiangsu province of China, and itscorrelation with the six criteria air pollutants, and air quality index (AQI). The present analysis willsupplement the limited understanding on the relation between the regions prevalent climatic conditionsand atmospheric pollution. The meteorological data analysis showed Suzhou city located in thesouthern region of the Jiangsu province with high average temperature, relative humidity, and rainfall.Maximum values of temperature, UV index, sunshine, relative humidity, and rainfall occurred duringsummer, while air pressure in winter. High values of all meteorological parameters occurred in thenorthern and southern region of the province. The data correlation study revealed AQI to havenegative correlation with most meteorological parameters, and positive correlation with air pressure inall cities.
Показать больше [+] Меньше [-]Removal of Iron from Aqueous Solution by using Typha australis Leaves as Low Cost Adsorbent Полный текст
2022
N’Dah, Fatimetou Mohamed | Sid’Ahmed Kankou, Mohamed | Abdallahi Bollahi, Mohamed | N’diaye, Abdoulaye Demba
Iron removal from aqueous solution via ultrasound-assisted adsorption using Typha australis leaves as low cost adsorbent had been studied. The effects of various experimental parameters like mass of the Typha australis adsorbent and contact time have been investigated using a batch experiment. The adsorption kinetic data were analyzed using the Pseudo First Order (PFO) and Pseudo Second Order (PSO) models. The adsorption modeling was carried out using the Langmuir, Freundlich and Redlich-Peterson adsorption models. For kinetic study, the adsorption process fitted the PSO model and agreed with chemisorption. Both the Langmuir and Redlich–Peterson models were found to fit the adsorption isotherm data well, but the Redlich– Peterson model was better. The maximum adsorption capacity from the Langmuir model (qmax) was 0.84 mg/g. The results of the present work showed that the Typha australis leaf, without any treatment has a good potential for iron removal from aqueous solutions via ultrasound-assisted adsorption.
Показать больше [+] Меньше [-]Temporal Monitoring and Effect of Precipitation on the Quality of Leachate from the Greater Casablanca Landfill in Morocco Полный текст
2022
Zaki, Khadija | Karhat, Youness | El Falaki, Khadija
A monthly temporal monitoring of the physico-chemical parameters of the leachate from the Greater Casablanca “Mediouna” open-air landfill in Morocco over a period of 13 months was carried out to show their variability over time. This monitoring also highlights the effect of rainfall on leachate quality through fluctuations observed in wet and dry periods. Indeed, the leachate was sampled from a collector that drains a mixture of young and mature leachate. Several physico-chemical parameters were studied: pH, temperature, conductivity, organic matter (BOD5 and COD), total matter (TS, TVS), nitrogen (N-NO2-, N-NO3-, N-NH4+, TKN), total phosphorus (Tp), salts (Cl-, SO42-) and metals (Cd, Co, Cr, Ca, Cu, Fe, K, Mg, Mn, Ni, Pb, Zn). As a result, significant concentrations were recorded throughout the monitoring for the majority of the parameters, showing a high aggressiveness of the leachate. Also, statistically significant relationships were observed between the different parameters. On the other hand, the leachate pollution index (LPI) was calculated to determine the overall potential of leachate pollution. The identification and study of the behaviour of the physico-chemical parameters is very useful for the design of an adequate leachate treatment plant for the Greater Casablanca landfill "Mediouna", taking into consideration the extreme values recorded during the monitoring period, in order to avoid any malfunctioning due to an underestimation of the pollution.
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