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Bioremediation of Heavy Metals by Use of Bacteria
2022
Orcan Demircan | Abdul Razaque Memon
Heavy metal pollution generally occurs due to socio-economic, industrial, and anthropogenic activities, which may cause an environmentally hazardous and serious severe threat to the survival of the organisms (genotoxic, carcinogenic, and clastogenic effects on it). Many physical and chemical remediation approaches have been proposed to deal with this pollution, but these are very time-consuming and costly. While bioremediation stands out as an inexpensive and efficient approach, the use of bacteria is thought to be a potential and productive organism to prevent this pollution. This review has evaluated the bacterial potential to clean up heavy metals from the environment and elucidated the mechanisms responsible for bioremediation.
Показать больше [+] Меньше [-]Assessment of Metal Levels in Biotic and Abiotic Materials from Giresun Forests
2020
Mustafa Türkmen | Aysun Türkmen | Ayhan Kara
The study investigated the metal levels in biotic and abiotic materials from Giresun forests. While soil and water samples were selected as abiotic materials, leaves and moss were selected as biotic materials in forest. These selected materials were sampled from six stations. All samples were analyzed three times for arsenic, iron, chromium, copper, manganese, nickel, lead and zinc by ICP-OES. A logarithmic transformation was done on the data to improve normality. One way ANOVA and Duncan’s multiple range tests were performed to test the differences among metal levels of stations. The differences among metal levels in stations were statistically significant (p
Показать больше [+] Меньше [-]Determination of Molybdenum Contents and Relation of Some Heavy Metals in the Soil of Meadow-Pasture Terraces Between Kırıkhan-Reyhanlı
2019
Mehmet Yalçın | Kerim Mesut Çimrin
This study was aimed to determine the molybdenum content of meadow - pasture soil between Kırıkhan and Reyhanlı in Hatay province and to determine the relations of the molybdenum content with some heavy metals in the soil. For this purpose, two different depths (0-20 and 20-40 cm) representing grassland pasture lands and 80 soil samples from 40 different points were taken. Cadmium (Cd), Cobalt (Co), Nickel (Ni), Lead (Pb), Copper (Cu), Iron (Fe), and Molybdenum (Mo) contents were determined in the soil samples. The contents of the available Cd, Co, Pb, Cu, Fe, Ni and Mo of the soil were determined by reading the 0.005 M DTPA + 0.01 M CaCl2 + 0.1 M TEA extracts in the ICP instrument. The results of the research shows that the Cd contents of the soils are between 0.01-0.32 ppm; Co contents are from 0.01 to 4.97 ppm; Ni contents 0.00 to 20.00 ppm; Pb contents 3.00-67.00 ppm; Cu contents 0.26-7.48 ppm; The Fe contents are between 4.00 and 61.00 and the Mo contents are between 0.001 and 0.064 ppm. It was determined that there are significant positive relationships between Co, Ni, Pb, Cu and Fe contents of Mo in the soil. It was also determined that there are significant positive significant relationships between Cd and Co; Co with Ni, Pb, Fe and Pb and Cu, Fe and Cu and Fe. No heavy metal pollution was found when the heavy metal contents of the regional soils were compared with the limit values.
Показать больше [+] Меньше [-]Conformity of Fruit Nectar Samples to Libyan Specification Standards
2016
Ahmeda Algari Alzagtat | Rema Yousef Eledody
The aim of this study is to evaluate the quality characteristics of physical, chemical and microbiological of some fruit nectar samples produced from some local and imported companies and sold in the city of Tripoli, and to determine their conformity with Libyan specification standards. In this study, 40 samples of different fruit nectars (grape, pineapple, guava, orange, apple, and mixed fruits) were collected from different local supermarket, five imported companies and 4 domestic which were available at the time of study. The Samples were classified based on their type of fruit nectars and also marked as (A, B, C, D) and (E, F, L, M, N) for different domestic or imported and imported companies respectively. The results showed that all the samples were free from artificial colours added. Local and imported samples were conform with the Libyan specification standards (990-2014) for fruit nectars. Five local and four imported samples were unconfirmed with the standards. In terms of acidity, some local and imported samples were conform to the Libyan specification standards, except one local sample and 5 imported samples. However, 35.3% of local samples and 43.5% of the imported samples unconfirmed to the Libyan standard specifications. Microbiological results showed that all local and imported samples were free from total bacterial count, yeasts and molds and coliform bacteria. Heavy metals (cadmium, lead, arsenic, copper, zinc, iron) of local and imported samples were conform to the Libyan specification standard, except 3 samples of imported products were had higher arsenic concentration. Based on the results of this study which indicated the importance of quality control programs for such products not only during production but also during storage and sales due to possibility of contamination and spoilage.
Показать больше [+] Меньше [-]The Effect of Leonardite on Chromium Toxicity and Growth of Cordes Rose
2022
Ayşen Akay | Mohammed Yashar Omar
High concentrations of chromium in the soil have a toxic effect on the living organisms in the soil ecosystem. If chromium, which is not an absolute essential element, accumulates in plants, it causes structural changes, causing a decrease in plant growth and also high toxicity due to its accumulation in biomass. Use of plants to remove chromium (Cr) from contaminated soils, it is an environmentally efficient, cost-effective, modern, applicable technique. The different species of plant and ornamental plants are used in this technique. In this study, the Kordes shrub rose used in landscaping in our province, Cr phytoremediation capacity was evaluated by growing at contaminated soil with Cr. In the study, the different doses of Cr (0, 50, 100, 500, 1000 mg kg-1) have been applied in Cr+3 and Cr+6 forms. In addition, two doses (0% and 3%) of leonardite were added to the pots to determine the effect on the developmental status of the plants and Cr uptake. In the study, plant height, number of branches, number of flowers, flower diameter, stem diameter, flower yield values and total wet and dry weight values at the end of the experiment were determined. At the end of the experiment, it was observed that generally developmental status of the plants was adversely affected at high Cr doses. Especially at 500 and 1000 mg kg-1 application doses was observed that the plants could not withstand Cr toxicity in a short time. It has been observed that plants treated with leonardite were healthier than those without. According to the data obtained at the end of the study, it was determined that the resistance of plant to high doses of Cr was low, but it showed better growth at 50 and 100 mg kg-1 doses.
Показать больше [+] Меньше [-]Monitoring of Heavy Metal Pollution in Water and Sediments at the Mid-Black Sea Region by Using Passive Sampling Method Diffusive Gradients in Thin Films
2021
Arife Şimşek | Şule Sancak | Gülfem Bakan
Determining the potential bioavailability of heavy metals, evaluating according to adapted regulations is essential to efficiently conserve our coastal and estuarine waters. In this study, it is aimed to determine the industrial pollution and various other pollution sources that the Black Sea Basin is exposed to by using DGT (Diffusive Gradients in Thin Films) method and grab (manuel) sampling method in water and sediment and to evaluate the existing pollution according to quality standards. In Samsun, seasonal samples were collected from five different sampling stations, namely Akkiraz Stream, Hıdırellez Stream, Organized Industrial Zone (OIZ) Channel, Şabanoğlu Stream and Selyeri Stream, which are selected from Tekkeköy region where industry is intensively active. In order to determine the heavy metal content in both water and sediment samples, the DGT method was chosen for passive sampling and the grab sampling method was used for active sampling, and the efficiency of the methods was evaluated. According to the results of the study, the heavy metal concentration in grab sampling for water samples in descending order Al> Fe> Zn> Pb> Ni> Cu; In the samples taken with DGT, they are listed as Al> Fe> Zn> Cu> Ni> Pb. There were significant relationships between the total metal concentrations of sediment (Csed) and water (Csu) in grab sampling and metal concentrations sediment (Csed-DGT) and water (Csu-DGT) measured by DGT. It was found that the sensitivity and performance of sampling with DGT was 2-10 times higher compared to grab sampling. The high resolution in situ DGT technique for the assessment and management of the potential release risk of heavy metals at the water-sediment interface is a complementary method that contributes to the standard grab sampling method.
Показать больше [+] Меньше [-]Polycyclic Aromatic Hydrocarbon and Metal Concentrations in Imported Canned Maize
2014
Embbey K Ossai | Chukwujindu Maxwell Iwegbue | Elizabeth E. Ajogungbe | Godswill O Tesi
Concentrations and profile of polycyclic aromatic hydrocarbons(PAHs) and metals (Cd, Pb, Ni, Cr, Fe and Mn) were determined in selected brands of canned maize in the Nigeria market with a view to providing information on the hazards associated with the consumption of these products. The measurement of the concentrations of PAHs was carried out by using a gas chromatography equipped with flame ionization detector (GC-FID) after extraction by ultra-sonication with acetone/dichloromethane and clean-up. The 16 PAH concentrations varied between 45.1 and 335.7 µg/kg. The concentrations of the indicators for occurrence and effects of PAHs in food varied from 3.6 to 114.5 µg/kg for BaP, 6.4 to 168.2 µg/kg for PAH2, 11.8 to 232.7 µg/kg for PAH4 and 19.4 to 327.3 µg/kg for PAH8. The concentrations of metals were determined by using atomic absorption spectrometry after acid digestion. The concentrations of metals in these samples ranged from
Показать больше [+] Меньше [-]Determination of Heavy Metal Remediation to Soil from Community Buildings’ Rooftop
2022
Yasin İlhanlı | Erman Ulker
Considering the importance of water in the world, the amount of usable water is not sufficient throughout the world, the existing available fresh water resources are not enough, therefore, water shortages may be encountered in the following years. Keeping the quality of water as it is demanded gains more importance than before. Particularly, heavy metals begin to interfere with groundwater resources, and the quantity of pollution growing due to industrialization, and urbanization. In the present study, the quantitative analysis of heavy metals in harvested rainwater from the rooftop of public buildings in Bornova, Izmir is investigated. The results show that a minimum of 5 μg of copper, 4 μg of zinc, 2.69 μg of lead, 0.095 μg of cadmium, 0.55 μg of chromium, 89,7 μg of iron, 0.96 μg of arsenic, 0.0119 μg of mercury and 3.88 μg of nickel should be tossed away for obtaining a liter of potable water. In conclusion, first flush diverters are recommended to convert these non-point pollutants to point source. Thus, municipalities can take necessary measures to protect the environment such as using phytoremediation and hyperaccumulator plants in sewages.
Показать больше [+] Меньше [-]The Effect of Foliar Application of Different Amino Acids (L-Histidine, Methionine) on Cadmium and Zinc Uptake of Wheat
2022
Özlem Ete Aydemir | Kürşat Korkmaz | Faruk Özkutlu
In this study, the effect of foliar L-Histidine and Methinonin amino acid applications on grain cadmium (Cd) and zinc (Zn) uptake on durum wheat grown in soil contaminated with Cd was investigated. The research was carried out according to the randomized blocks design as a pot experiment in greenhouse conditions. In the experiment, Cd doses were applied as control (0 mg Cd kg-1) and (3 mg Cd kg-1). L-Histidine and Methionine amino acids were applied 7 times from the leaf after the start of flag leaf formation in wheat at 0.5 mM doses and harvested after the grain maturity was completed. According to the results obtained, the wheat grain dry matter yield in 3 mg Cd kg-1 polluted soil was 44.5 mg grain-1 in the control, while the dry matter weight was increased with the application of L-Histidine and Methionine from the leaves being 48 and 50 mg grain-1, respectively. It was determined that there were differences in grain Cd and Zn concentrations with the application of amino acids from the leaves at the dose of 3 mg kg-1 cadmium. When the grain Cd and Zn intakes were compared with the control, it was found that the grain Cd concentration decreased, and the Zn concentration increased as a result of the application of amino acids. The high amount of Cd in wheat can make it to the human body through the food chain and is known to cause serious health problems after a certain amount of accumulation. As a result of this study, it is seen that L-Histidine and Methionine are effective in reducing Cd in the grain, and these amino acids probably form a complex with Cd, resulting in less transport.
Показать больше [+] Меньше [-]Determination of Heavy Metals in Locally Available Chocolates in Lahore Region
2021
Muhammad Amjad | Shabbir Hussain | Zia Ur Rehman Baloch | Aoun Raza
Heavy metal toxicity can either be acute or chronic effects. Long-term exposure of the body to heavy metal can progressively lead to muscular, physical and neurological degenerative process. In this research, a total of 30 representative chocolate samples were collected from local shops and markets in Lahore. All the samples were analysed to assess the levels of Lead (Pb), Nickel (Ni), Chromium (Cr) and Cadmium (Cd) by using Atomic Absorption Spectrophotometer in Pakistan Council of Scientific and Industrial Research (PCSIR), Lahore. It was observed that the majority of chocolate samples contain heavy metals levels higher than the permissible limits as recommended by Punjab Food Rules (PFR) 2011. The levels of Pb ranged between 0.375 and 3.4 mg/kg with 90% samples having concentrations exceeding PFR allowable limit (0.5 mg/kg). Whereas, Ni concentrations varied from 0.005 to 0.28 mg/kg and 80% samples were above the PFR limit (0.025 mg/kg). Further, Cr levels analysed between 0.005 to 0.28 mg/kg and 53% samples had Cr concentrations higher than PFR limit (0.02 mg/kg). Similarly, Cd levels were observed between 0.50-3.25 mg/kg with 53% samples having Cd concentrations exceeding the PFR limit (1.0 mg/kg). Investigation indicates that the quality of available chocolates is not recommendable for eating because of the higher concentrations of toxic heavy metals.
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