Microemulsions are thermodynamically stable systems that have attracted considerable attention in the food industry as delivery systems for many hydrophobic nutrients. These spontaneous systems are highly dependent on ingredients and composition. In this work phase diagrams were constructed using two surfactants (Kolliphor RH40 and ELP), water, sunflower oil, and ethanol as cosurfactant, evaluating their physicochemical properties. Stability of the systems was studied at 25 and 60 °C, monitoring turbidity at 550 nm for over a month to identify the microemulsion region. Conductivity was measured to classify between water-in-oil and oil-in-water microemulsions. The phase diagram constructed with Kolliphor RH40 exhibited a larger microemulsion area than that formulated with Kolliphor ELP. All formulations showed a monomodal droplet size distribution with low polydispersity index (<0.30) and a mean droplet size below 20 nm. Systems with higher water content presented a Newtonian behavior; increasing the dispersed phase content produced a weak gel-like structure with pseudoplastic behavior under flow conditions that was satisfactorily modeled to obtain structural parameters. | Fil: Mori Cortés, Noelia. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina | Fil: Lorenzo, Gabriel. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina | Fil: Califano, Alicia Noemi. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentina

Food grade W/O microemulsions were developed and characterized to be used in blends with sunflower oil as replacers of palm kernel oil in whipped cream alternatives. Creams for whipping are oil-in-water (O/W) emulsions containing significant proportions of partially hydrogenated solid fat. With the addition of sunflower oil and W/O microemulsions up to 6.8% w/w in the final confectionary product we achieved the decrease of saturated fats and also the decrease of the energy required for the formulation. More specifically, by replacing 20% w/w of the oil phase by the proposed edible W/O microemulsions, the homogenization time was reduced from 7 to 5min under the same experimental conditions. In addition solid fat partial replacement permitted the modification of structural and textural characteristics. Droplet size and size distribution measurements were performed using dynamic light scattering (DLS). The existence of rather polydisperse oil droplets with diameters of approximately 1μm upon palm kernel oil partial replacement was detected. Structural characterization of the proposed alternative systems with confocal laser scanning microscopy (CLSM) showed the existence of air bubbles of diameter 6–94μm stabilized by globular oil droplets having diameters ranging from 4.2 to 5.9μm adhered to their surface. Firmness and consistency of the proposed alternative formulations were evaluated using a Stevens-texture analyzer. As a result emulsions after whipping gave products with lower density (362±9g/mL) but higher consistency (208±7g) as compared to the standard whipped cream preparation (150±5g).