In the tropics, the water potential of a region cannot be adequately assessed from precipitation alone due to the seasonal character of rainfall and even more so owing to the changing climate scenario. It is therefore necessary that in any agro-climatological program, there must be a clear understanding of the actual amount of water that evaporates and transpires (AET), and the amount of water that would evaporate and transpire if water were always readily available (PET). This could be done through the method of the water balance. The present work examines the water budget of parts of the Imo river basin and its implications for improved crop production through supplementary irrigation schedules. It was observed, that the study area is already facing moisture-stress. This is because even during rainy months supplementary irrigation is required to compensate for the occasionally moisture deficit due to increased evapotranspiration. The study showed that cultivation of maize, rice and tomatoes can be carried out on an all-year round basis under a scientific irrigation scheme. Thus the study provided farmers with guideline on the period and quantity of water required for supplementary irrigation, a development which will prevents wilting of plants before the application of needed water.

The aim of this study was to compare the transfer of primary aromatic amines (PAAs) from napkins into cold water extract (CWE) with transfer into four different food matrices. An HPLC-MS/MS multi-analyte method for quantification of 26 PAAs in CWE was validated and applied. In addition, the method was validated for seven different PAAs in four different food matrices (cucumber, rice, pickled gherkin and butter cookie) representing wet, dry, acidic and fatty food. The CWEs of 12 coloured napkin samples were analysed, and 3 napkins released more than 0.01 mg kg-1 PAAs into the CWE. These three napkins were chosen for transfer testing with food samples. In total, seven different PAAs were quantified in the food samples. Results show that the transfer of the tested PAAs into the CWE is in most cases comparable to the transfer into the tested food samples. In some cases, the CWE overestimates transfer into food, except for the transfer of aniline into pickled gherkin, where the CWE underestimates transfer. Therefore, the CWE serves as an adequate and certainly not overestimating simulation of reality for the tested transfer of PAAs into the food samples.