Metallophytes for organic synthesis: towards new bio-based selective protection/deprotection procedures

Grison, Claire M.; Velati, Alicia; Escande, Vincent; Grison, Claude

Metallophytes for organic synthesis: towards new bio-based selective protection/deprotection procedures

2015

Grison, Claire M. | Velati, Alicia | Escande, Vincent | Grison, Claude

We propose for the first time using metal hyperaccumulating plants for the construction of a repertoire of protection and deprotection conditions in a concept of orthogonal sets. Protection of alcohol, carbonyl, carboxyl, and amino groups are considered. The ecocatalysts derived from metal-rich plants allow selective, mild, eco-friendly, and efficient protection or deprotection reactions. The selectivity is controlled by the choice of the metal, which is hyperaccumulated by the metallophyte.

显示更多 [+]