Metallophytes for organic synthesis: towards new bio-based selective protection/deprotection procedures
2015
Grison, Claire M. | Velati, Alicia | Escande, Vincent | Grison, Claude
We propose for the first time using metal hyperaccumulating plants for the construction of a repertoire of protection and deprotection conditions in a concept of orthogonal sets. Protection of alcohol, carbonyl, carboxyl, and amino groups are considered. The ecocatalysts derived from metal-rich plants allow selective, mild, eco-friendly, and efficient protection or deprotection reactions. The selectivity is controlled by the choice of the metal, which is hyperaccumulated by the metallophyte.
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