Phosphoryl- und Thiophosphoryl-schwefeloxiddifluoridimide / Phosphoryl- and Thiophosphoryl-sulfuroxidedifluorideimides

Feser, Manfred; Höfer, Rainer; Glemser, Oskar

Phosphoryl- und Thiophosphoryl-schwefeloxiddifluoridimide / Phosphoryl- and Thiophosphoryl-sulfuroxidedifluorideimides

2014

Feser, Manfred | Höfer, Rainer | Glemser, Oskar

The phosphorylhalides OPF₂Cl, OPFCl₂ and OPCl₃ react with Ag+NS(O)F₂- (1) to yield the phosphorylsulfuroxidedifluorideimides (2)—(7). Reaction of SPCl₃ and 1 yields the thiophosphorylhalides SPCl₃₋ₙ(NSOF₂)ₙ, and by decomposition of 11 SPF(NSOF₂)₂ is formed. The IR, mass, ¹H, ¹⁹F and ³¹P NMR spectra of the above mentioned compounds are reported.

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