Reaktionen von Re2O7 mit Iminophosphoranen - Kristallstruktur von (O3ReN = PPh2)2C2H4/Reactions of Re2O7 with Iminophosphoranes - Crystal Structure of (O3ReN = PPh2)2C2H4

Roesky, H. W.; Hesse, Detlev; Rietzel, Mathias; Noltemeyer, Mathias

Reaktionen von Re2O7 mit Iminophosphoranen - Kristallstruktur von (O3ReN = PPh2)2C2H4/Reactions of Re2O7 with Iminophosphoranes - Crystal Structure of (O3ReN = PPh2)2C2H4

2014

Roesky, H. W. | Hesse, Detlev | Rietzel, Mathias | Noltemeyer, Mathias

Re₂O₇ reacts with (Me₃SiN = PPh₂)₂CH₂, (Me₃SiN = PPh₂)₂C₂H₄ and Me₃SiN = PPh₃ to give (O₃ReN = PPh₂)₂CH₂ (3), (O₃ReN = PPh₂)₂C₂H₄ (6) and Ph₃P= NReO₃ (7). 6 has been characterizedby X-ray crystallography. The complex crystallizes in the space group P 1̄ with unit cell dimensions a = 837.4(4), b = 873.0(5), c = 1102.5(6) pm, ɑ = 112.53(4), β = 98.54(4), γ = 100.59(4)°, and Z = 1. The structure demonstrates that the bis(diphenylphosphinimino)-ethane group is bridging two ReO₃ units.

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