As an inevitable industrial by-product, polyaluminum chloride residue (PACR) will cause serious harm to the environment if directly buried and dumped. The aim of this paper was searched a new economical, environmental, and practical way of utilization for PACR. In this paper, a novel non-burning PACR compound filler was made from mainly PACR. The prepared compound filler has excellent physical properties and phosphate adsorption efficiency of up to 99.9%. Static adsorption experiments showed that the adsorption process of phosphorus by the compound filler conformed to the pseudo-second-order kinetic model and intra-particle diffusion model. Langmuir and Freundlich isotherm models described the phosphorus adsorption process well, and the maximum phosphate adsorption capacity arrived at 42.55 mg/g. The phosphate adsorption by the compound filler is a spontaneous endothermic process. The main mechanisms are ligand exchange and Lewis acid-base interactions; calcium and aluminum play important roles in the adsorption of phosphorus by the compound filler. Dynamic column experiments showed that as much as 90% of the phosphorus removal by compound filler, and the phosphorus concentration decreased from 1 to ~0.1mg/L. The results provide a new waste resource utilization method for PACR and show the good application potential of prepared compound filler in constructed wetlands.

The Fifth Ministerial Conference on Environment and Development in Asia and the Pacific (MCED-5) provided a regional implementation plan to pursue economic development in Asia-Pacific. Achieving environmentally sustainable economic growth or green growth is considered necessary by the ministerial declaration of the conference. The ministerial declaration defines green growth as an approach to sustaining economic growth and employment creation, a prerequisite for effective poverty reduction while coping with natural resource constraints and climate change. Based on the importance of green growth, the study seeks to investigate the progress towards sustainable economic development in Pakistan from 1990 to 2019. The study employs structural equation modeling (SEM) to determine the direct and indirect effects of the variables of the green growth model adopted in the MCED-5. The results of the study indicate that an increase in the net national income of the country leads to increased natural resource depletion. The declining stock of natural capital points towards the difficulty in fulfilling biocapacity sustainability in Pakistan while achieving social progress and declining carbon intensity in the quest for sustainable development. Based on the analysis, it can be claimed that the negative impact of increasing inclusive wealth on natural capital makes Pakistan in environmental terms a weakly sustainable nation. Thus, the conclusion is that Pakistan is following a path of weak sustainability. As a result, there is a need to shift the country’s sustainable economic development from weak sustainability to strong sustainability if the increasing natural resource depletion is to be restrained.

Waste incineration is a process of full combustion reaction between waste and oxygen at high temperature. It is a new problem whether the special natural environmental conditions of Tibet Plateau, such as low air pressure, low oxygen content, and low temperature, will affect the waste incineration in the plateau area. In this work, the influence of different parameters on MSW incineration efficiency and flue gas emission were investigated. The results showed that the temperatures exhibited a significant impact on the flue gas emission. Under the lower temperature, CO was determined to be the main pollutant. With the increase of temperature, NOx became the main pollutant. The optimal temperature range of flue gas emission was between 800 and 900°C. A slight negative pressure in incinerator was benefit for incineration system safety and flue gas emissions. The optimal range was −50 to 0Pa. Lower oxygen content (3–6%) in the incinerator affected the incineration efficiency and flue gas emission. Meanwhile, the high oxygen content had no obvious impact on the flue gas emission, but the cost increased and the service life of the incinerator was affected. The optimal oxygen content in the incinerator was controlled at 6–8%. Furthermore, the air temperatures, pressures, and oxygen content in the natural environment had no significant effect on MSW incineration process. Increasing the air volume would bring about the increase of N₂ in the incinerator. This work provides the basic data support for MSW incineration technology in plateau area.

Spatial and temporal variations in soil denitrification and anaerobic ammonium oxidation (anammox) across the freshwater-oligohaline wetlands in subtropical estuary have not been well understood. In this study, continuous-flow soil core incubation combined with nitrogen isotope tracer was used to determine denitrification and anammox rates across freshwater-oligohaline tidal wetlands in Min River Estuary, Southeast China. Areal rates of denitrification and anammox varied from 3.89 to 19.0 μmol m⁻² h⁻¹ and from 0.15 to 1.11 μmol m⁻² h⁻¹, respectively, across these wetlands and throughout sampling months. Denitrification rates were higher in warm months (July, September) than in cool months (November, January), whereas anammox did not vary significantly across the sampling months. Average denitrification rates throughout the sampling months were higher in freshwater than in oligohaline wetlands, while anammox rates did not vary among the wetlands. Relative contribution of anammox (Rₐ) to N₂ production (including denitrification and anammox) varied from 1.03 to 18.3% across the sampling months and wetlands. Denitrification rates differed significantly across the wetlands and sampling months. Anammox rates and Rₐ did not vary significantly among the sampling months. Denitrification rates were positively correlated with water content, total organic carbon (TOC), total nitrogen, dissolved organic nitrogen, NH₄⁺, NOₓ–, Fe²⁺, and Fe²⁺/Fe³⁺, but negatively related to pH. Anammox rates showed negative relationships with water content and TOC. Water content, temperature, and pH were crucial for organic carbon and Fe²⁺ availability with important implications on denitrification and anammox. Therefore, denitrification rates vary significantly, whereas anammox rates do not vary significantly across freshwater-oligohaline wetlands in the Min River Estuary.

Monitoring of pollution in the vicinity of roads connected to winter road maintenance is one of the important tools for optimising winter maintenance technology and reducing its environmental impact. The aim of this study was to determine the relationship between winter road maintenance and the increased concentration of sodium ion to characterise the harm caused by the de-icing agents on selected types of individual components grown in the Norway spruce ecosystem. The model area is located in the immediate vicinity of the D1 motorway connecting Prague and Brno (Czech Republic), at 103 km. The area is thus exposed to long-term contamination from automobile transport, and the monitoring was carried out for 3 consecutive years. A clear effect of the de-icing agents on conifers near the road has been demonstrated by the symptoms of salt damage visually observed in close proximity to the road (at a sampling distance of 5 m). The needles of these spruce trees also showed increased sodium concentrations, regardless of the age of the needles. The study also confirms that sodium accumulates in all selected components of the analysed ecosystem (moos, humus, soil). The sodium concentration has been found to decrease with increasing distance from the road for all of the components.

Plastic pollution has become a serious transboundary challenge to nature and human health, with estimation of reports published — predicting a twofold increase in plastic waste by 2030. However, due to the COVID-19 pandemic, the excessive use of single-use plastics (including face masks, gloves and personal protective equipment) would possibly exacerbate such forecasts. The transition towards eco-friendly alternatives like bio-based plastics and new emerging sustainable technologies would be vital to deal with future pandemics, even though the use or consumption of plastics has greatly enhanced our quality of life; it is however critical to move towards bioplastics. We cannot deny the fact that bioplastics have some challenges and shortcomings, but still, it is an ideal option for opt. The circular economy is the need of the hour for waste management. Along with all these practices, individual accountability, corporate intervention and government policy are also needed to prevent us from moving from one crisis to the next. Only through cumulative efforts, we will be able to cope up with this problem. This article collected scattered information and data about accumulation of plastic during COVID-19 worldwide. Additionally, this paper illustrates the substitution of petroleum-based plastics with bio-based plastics. Different aspects are discussed, ranging from advantages to challenges in the way of bioplastics.

Acyclovir (ACV) is a commonly used antiviral drug; however, its poor bioavailability can lead to at least ng/L level residue in natural water. Sulfate radical, produced from persulfate (PS) by zero-valent iron (ZVI) activation, was demonstrated to effectively degrade ACV in this study. Influencing parameters, including ZVI dose, PS usage, initial ACV concentration, solution pH, and temperature, were evaluated to find the optimal degradation conditions. Intermediates were identified and main degradation pathways were proposed. Experiments showed that ACV degradation by ZVI/PS oxidation followed a pseudo zero-order reaction well (R² > 0.99). At pH ≦ 9, the optimal combination was 0.4 mM PS with 1.2 mM ZVI, in order to completely remove 10 μM ACV during 60-min reaction. Heat activation of PS would hinder the effect of ZVI if temperature was 45 °C or above. ACV could be oxidized to four major degradation products, including methoxyacetic acid (P1, C₃H₆O₃, m/z = 91), 1,1,2-trinitroethane (P2, C₂H₃N₃O₆, m/z = 165), trinitromethane (P3, CHN₃O₆, m/z = 151), and dinitromethane (P4, CH₂N₂O₄, m/z = 105). Though the mineralization rate was not high (about 24.0%), ZVI/PS oxidation was proved to be an available treatment method for ACV-induced water pollution.

Exposure to fine particulate matter can easily lead to health issues. PM₂.₅ concentrations are associated with various spatiotemporal factors, which makes the prediction of PM₂.₅ concentrations still a challenging task. One of the reasons that makes the accurate prediction by statistical learning method difficult is severe fluctuations in input data. In addition, the abstraction method of space will also affect the prediction results. To address these important issues, a novel hybrid decomposing-ensemble and spatiotemporal attention (DESA) model is proposed to improve the prediction accuracy by decomposing the mode-mixed time series into single-mode series and automatically assign weights to the spatiotemporal factors. In our proposed framework, raw PM₂.₅ series are firstly decomposed into simple sub-series via the complete ensemble empirical mode decomposition (CEEMD) method. Then, to keep the results independent of the spatial abstraction method, a data-driven approach called multiscale spatiotemporal attention network is employed to extract spatiotemporal features from the sub-series. Finally, the predictions of each sub-series are processed separately and combined to obtain the final prediction results. The experimental results indicate that the proposed model achieved the better performance with RMSE of 11.15, 17.49, 24.84, and 26.93 for 6-, 12-, 24-, and 36-h forecasting, respectively. The proposed method is expected to be applied in fine prediction of air pollution and controlling programs and therefore provide decision support or useful guidance.

Sugarcane cultivars (Saccharum officinarum L.) are widely cultivated for both sugar and renewable energy in China. The response of rhizosphere fungal composition and diversity to different emerging sugarcane cultivars is limited. Therefore, utilizing high-throughput sequencing, we explored fungal communities’ structure in soils adhering to six sugarcane cultivars’ roots (Guitang 08–120, Regan14-62, Guitang 08–1180, Haizhe 22, Liucheng 05–136, Taitang 22) in Guangxi Province, China. Our results suggested that sugarcane varieties significantly altered rhizosphere soil attributes, with Haizhe 22 having substantially lower soil pH, organic matter (OM), available phosphorus (AP), and soil water contents (SWC) than others cultivars. Different sugarcane varieties did not substantially affected the Shannon fungal diversity index, but the apparent effect on fungal richness was significant. Beta diversity analysis revealed that “Haizhe 22” distinguished the fungal community from the other five cultivars. Soil pH, OM, cultivars, and soil moisture were crucial determinants in shaping soil fungal composition. The Haizhe 22 rhizosphere significantly enriched the operational taxonomic units (OTUs) assigned to two fungal genera (Cephalotheca and Sagenomella), while rhizosphere of other verities significantly enriched the OTUs assigned to four fungal genera (Chaetomium, Chaetosphaeria, Mortierella, and Talaromyces), suggesting their essential role in plant development, disease tolerance, and bioremediation. These findings may help in selecting or breeding innovative genotypes capable of supporting abundant rhizosphere fungi beneficial to plants that would likely improve crops’ agronomic potential and maintain soil ecosystem sustainability.

Water quality deterioration is a prominent issue threatening water security worldwide. As the largest river in China, the Yangtze River Basin is facing severe water pollution due to intense human activities. Analyzing water quality trends and identifying the corresponding driver factors are important components of sustainable water quality management. Thus, spatiotemporal characteristics of the water quality from 2008 to 2020 were analyzed by using a Mann–Kendall test and rescaled range analysis (R/S). In addition, multi-statistical analyses were used to determine the main driving factors of variation in the permanganate index (CODMₙ), ammonia nitrogen (NH₃–N) concentration, and total phosphorus (TP) concentration. The results showed that the mean concentrations of NH₃–N and TP decreased from 0.31 to 0.16 mg/L and 0.16 to 0.07 mg/L, respectively, from 2008 to 2020, indicating that the water quality improved during this period. However, the concentration of CODMₙ did not reduce remarkably. Based on R/S analysis, the NH₃–N concentration was predicted to continue to decrease from 2020 to 2033, whereas the CODMₙ concentration was forecast to increase, highlighting an issue of great concern. In terms of spatial distribution, water quality in the upstream was better than that of the mid-downstream. Multi-statistical analyses revealed that the temporal variation in water quality was predominantly influenced by tertiary industry (TI), the nitrogen fertilizer application rate (N-FAR), the phosphate fertilizer application rate (P-FAR), and the irrigation area of arable land (IAAL), with contribution rates of 15.92%, 14.65%, 3.46%, and 2.84%, respectively. The spatial distribution of CODMₙ was mainly influenced by TI, whereas that of TP was primarily determined by anthropogenic activity factors (e.g., N-FAR, P-FAR). This study provides deep insight into water quality evolution in the Yangtze River Basin that can guide water quality management in this region.