Phase equilibria of vegetable oils with near-critical fluids
1997
Fuente B, J.C de la | Fornari, T. | Brignole, E.A. | Bottini, S.B.
The application of the SRK equation of state for the prediction of the phase behaviour of mixtures of vegetable oils with near critical solvents is studied. The use of binary interaction parameters in the combinatorial rules for both the co-volume and the energy parameter is discussed. Two different sets of binary interaction parameters are needed in order to correlate the vapor-liquid and liquid-liquid equilibria. This indicates a serious limitation of van der Waals type of equations of state for modeling the phase equilibria of this type of systems.
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