Lewis acid-promoted cascade reaction for the synthesis of Michael acceptors and its application in a dimerization reaction

Zhao, Xiao-Jing; Zhao, Jie; Sun, Xin; Liu, Ji-Kai; Wu, Bin

Lewis acid-promoted cascade reaction for the synthesis of Michael acceptors and its application in a dimerization reaction

2017

Zhao, Xiao-Jing | Zhao, Jie | Sun, Xin | Liu, Ji-Kai | Wu, Bin

An efficient Lewis acid-promoted cascade reaction with dimethyl sulfoxide as a methylene source for the synthesis of Michael acceptors is reported. The key to developing this procedure is the selection of a mild base to modulate the equilibrium of various intermediates in order to drive the reaction forward to the formation of Michael acceptor and dimeric compound products. Extensive studies were performed to gain insight into a possible reaction mechanism.

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Palabras clave de AGROVOC

chemical structure

Información bibliográfica

Publicado en

Tetrahedron

ISSN 0040-4020

Editorial

Elsevier Ltd

Otras materias

Pummerer; Dimethyl sulfoxide; Dimethyl sulfoxide; Lewis acid; Dimerization; Dimerization; Michael acceptors

Idioma

Inglés

Nota

Pre-press version

Licencia

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Tipo

Journal Article; Text

En AGRIS desde: 2024-02-27

Formato: MODS

Proveedor de Datos

Este registro bibliográfico ha sido proporcionado por National Agricultural Library

Descubra la colección de este proveedor de datos en AGRIS

Enlaces

DOI http://dx.doi.org/10.1016/j.tet.2017.05.017

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