Lewis acid-promoted cascade reaction for the synthesis of Michael acceptors and its application in a dimerization reaction

Zhao, Xiao-Jing; Zhao, Jie; Sun, Xin; Liu, Ji-Kai; Wu, Bin

Lewis acid-promoted cascade reaction for the synthesis of Michael acceptors and its application in a dimerization reaction

2017

Zhao, Xiao-Jing | Zhao, Jie | Sun, Xin | Liu, Ji-Kai | Wu, Bin

An efficient Lewis acid-promoted cascade reaction with dimethyl sulfoxide as a methylene source for the synthesis of Michael acceptors is reported. The key to developing this procedure is the selection of a mild base to modulate the equilibrium of various intermediates in order to drive the reaction forward to the formation of Michael acceptor and dimeric compound products. Extensive studies were performed to gain insight into a possible reaction mechanism.

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Mots clés AGROVOC

chemical structure

Informations bibliographiques

Publié dans

Tetrahedron

ISSN 0040-4020

Editeur

Elsevier Ltd

D'autres materias

Pummerer; Dimethyl sulfoxide; Dimethyl sulfoxide; Lewis acid; Dimerization; Dimerization; Michael acceptors

Langue

anglais

Note

Pre-press version

Licence

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Type

Journal Article; Text

Sur AGRIS depuis: 2024-02-27

Format: MODS

Fournisseur de données

Cette notice bibliographique a été fournie par National Agricultural Library

Découvrez la collection de ce fournisseur de données dans AGRIS

Liens

DOI http://dx.doi.org/10.1016/j.tet.2017.05.017

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