Construction of β-Trifluoromethyl Enol Ether via Base-Promoted C–O Coupling and Rearrangement of Hydrogen Atom
2017
Dai, Kun | Wang, Guan | Li, Yang | Chen, Jian'gang | Liu, Zhong-Wen | Lu, Jian | Liu, Zhao-Tie
A novel, high-efficiency and high-selectivity construction of β-trifluoromethyl enol ether via base-induced/promoted C–O coupling of trifluoromethylated vinyl chloride and phenols is presented with a broad substrate scope. The reaction mechanism, especially the significantly high selectivity, was excavated and understood via DFT calculation and is well supported by the experimental observation.
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