The transport of water in four EVOH copolymers commonly used in high barrier food packages was characterized through permeation (continuous flow) and gravimetric experiments at different rela tive humidities and 23 ± 2°C. Water sorption isotherms were fitted with the D'Arcy and Watts' equa tion. From these data, the value of the solubility coefficient (S, as defined by Henry's law) was deter mined and was found constant within a 0.2-0.75 water activity (a w) range. Water uptake at the same a w increased as the EVOH ethylene content decreased. The permeability coefficient (P) for water through EVOH was determined as a function of water activity. The permeability was constant within the range of 0.3-0.75 a w and decreased with EVOH ethylene content. At high relative humidities (a w > 0.75) the value of permeability increased by up to two orders of magnitude. In this range, the higher the ethylene content the lesser the value of P.

Water is an essential component of food structures and biological materials. The importance of water as a parameter affecting virion stability and inactivation has been recognized across disciplinary areas. The large number of virus species, differences in spreading, likelihood of foodborne infections, unknown infective doses, and difficulties of infective virus quantification are often limiting experimental approaches to establish accurate data required for detailed understanding of virions’ stability and inactivation kinetics in various foods. Furthermore, non-foodborne viruses, as shown by the SARS-CoV-2 (Covid-19) pandemic, may spread within the food chain. Traditional food engineering benefits from kinetic data on effects of relative humidity (RH) and temperature on virion inactivation. The stability of enteric viruses, human norovirus (HuNoV), and hepatitis A (HAV) virions in food materials and their resistance against inactivation in traditional food processing and preservation is well recognized. It appears that temperature-dependence of virus inactivation is less affected by virus strains than differences in temperature and RH sensitivity of individual virus species. Pathogenic viruses are stable at low temperatures typical of food storage conditions. A significant change in activation energy above typical protein denaturation temperatures suggests a rapid inactivation of virions. Furthermore, virus inactivation mechanisms seem to vary according to temperature. Although little is known on the effects of water on virions’ resistance during food processing and storage, dehydration, low RH conditions, and freezing stabilize virions. Enveloped virions tend to have a high stability at low RH, but low temperature and high RH may also stabilize such virions on metal and other surfaces for several days. Food engineering has contributed to significant developments in stabilization of nutrients, flavors, and sensitive components in food materials which provides a knowledge base for development of technologies to inactivate virions in foods and environment. Novel food processing, particularly high pressure processing (HPP) and cold plasma technologies, seem to provide efficient means for virion inactivation and food quality retention prior to packaging or food preservation by traditional technologies.

Water vapour sorption isotherms describe the relationship between water content and water activity. Depending on the nature of food powder (crystalline or amorphous), the shape of isotherm is different. Mostly food powders have complex structures, including potentially crystallisable solutes such as sugars, which show changes in crystallinity during the adsorption of water. Even for such an apparently simple system as crystalline sugar, numerous factors affect the adsorption of water vapour and, as a consequence, the storage stability. The presence of a thin film of saturated solution at the surface of the crystal, grain size distribution and the inclusion of mother liquor droplets in the crystal are some of the factors which perturb the equilibrium relative humidity of sugar and its aptitude to caking. These conditions were carefully studied at the level of the laboratory and in a pilot silo. Conditions of "decaking" (recovering a flowing sugar after caking) were also established. In the case of noncrystalline powders, water activity, together with glass transition temperature, is important to determine if it is necessary to interpret the origin of the formation of bridges between food powder particles and the caking phenomenon.

Water content quantification of raw polysaccharide materials for food processing is generally performed by gravimetric analysis or titrimetric methods, which are time- and energy-consuming, non-eco-friendly and sample destructive. The present study develops and validates a new approach, based on the use of Fourier transform infrared (FTIR) spectroscopy, resulting in a model of the water content of carboxymethyl cellulose (CMC) polysaccharides. Samples of CMC were exposed to different relative humidity conditions. Water content was determined by standard gravimetric methods (OIV-Oeno 404–2010) and compared with the area of FTIR absorption in the range 3675–2980 cm⁻¹, attributed to the stretching of OH groups. The strong correlation between gravimetric results and FTIR area (R² = 0.88) showed no signs of bias across the water content range. A cross-validation technique to predict the water content by band area was assessed obtaining a general equation: y = 2.12 x + 2.80 with a high repetitively and good prediction of the tested models.

[Departement_IRSTEA]Ecotechnologies [TR1_IRSTEA]SPEE | To reduce the proliferation of bacteria inside food plants, cleaning and disinfection are performed daily following production. These operations are followed by drying during which the drying rate should be as high as possible. This study shows the influence of a dehumidifier on the water mass evolution on surfaces during the drying of a food plant. The temperature, relative humidity and water mass evolution were monitored under two conditions: with and without a dehumidifier. Comparison of the results shows that the drying rate is about 1.5 times higher when a dehumidifier is used. These data were used to develop a simplified heat and mass transfer model allowing the prediction of the temperature and drying rate at different locations. The results can help the manufacturer to evaluate the benefits of a dehumidifier and consider the use of other devices to achieve better airflow distribution or greater heat supply for certain surfaces.

One of the most common materials used for packaging is low density polyethylene film. To improve the water vapour transfer of the film, zeolite¡polymer composite films and perforated films are produced. The solid-low density polyethylene composite films were prepared by extrusion of polyethylene beads coated with hot zeolite particles of a definite size range in an industrial extruder (-420/+212, -212/+106, -106/+53 microparticles/g of polyethylene beads). A needle (0.2, 0.5 and 1.75 mm in diameter) attached to the tip of a soldering gun was used for the production of the perforated polyethylene films (1, 3, 6, 12, 18 and 24 holes per 38.5 cm2). The overall evaluation indicates that the water vapour transfer rates can be modified by the composite and the perforated films, which provides packaging material variety for foods of different moisture content. The solid- polyethylene composite films showed less permeability to water vapour than the polyethylene film. This may be attributed to two reasons: the available polyethylene area is reduced by the presence of solid particles and these solid particles have an important sorption property. The water vapour transfer rates increased by the perforated films.

Poverty, food insecurity and climate change are global issues facing humanity, threatening social, economic and environmental sustainability. Greenhouse cultivation provides a potential solution to these challenges. However, some greenhouses operate inefficiently and need to be optimized for more economical and cleaner crop production. In this paper, an economic model predictive control (EMPC) method for a greenhouse is proposed. The goal is to manage the energy-water‑carbon-food nexus for cleaner production and sustainable development. First, an optimization model that minimizes the greenhouse's operating costs, including costs associated with greenhouse heating/cooling, ventilation, irrigation, carbon dioxide (CO₂) supply and carbon emissions taking into account both the CO₂ equivalent (CO₂-eq) emissions caused by electrical energy consumption and the negative emissions caused by crop photosynthesis, is developed and solved. Then, a sensitivity analysis is carried out to study the impact of electricity price, supplied CO₂ price and social cost of carbon (SCC) on the optimization results. Finally, a model predictive control (MPC) controller is designed to track the optimal temperature, relative humidity, CO₂ concentration and incoming radiation power in presence of system disturbances. Simulation results show that the proposed approach increases the operating costs by R186 (R denotes the South African currency, Rand) but reduces the total cost by R827 and the carbon emissions by 1.16 tons when compared with a baseline method that minimizes operating costs only. The total cost is more sensitive to changes in SCC than that in electricity price and supplied CO₂ price. The MPC controller has good tracking performance under different levels of system disturbances. Greenhouse environmental factors are kept within specified ranges suitable for crop growth, which increases crop yields. This study can provide effective guidance for growers' decision-making to achieve sustainable development goals.

Natural biopolymers have become key players in the preparation of biodegradable food packaging. However, biopolymers are typically highly hydrophilic, which imposes limitations in terms of barrier properties that are associated with water interactions. Here, we enhance the barrier properties of biobased packaging using multilayer designs, in which each layer displays a complementary barrier function. Oxygen, water vapor, and UV barriers were achieved using a stepwise assembly of cellulose nanofibers, biobased wax, and lignin particles supported by chitin nanofibers. We first engineered several designs containing CNFs and carnauba wax. Among them, we obtained low water vapor permeabilities in an assembly containing three layers, i.e., CNF/wax/CNF, in which wax was present as a continuous layer. We then incorporated a layer of lignin nanoparticles nucleated on chitin nanofibrils (LPChNF) to introduce a complete barrier against UV light, while maintaining film translucency. Our multilayer design which comprised CNF/wax/LPChNF enabled high oxygen (OTR of 3 ± 1 cm³/m²·day) and water vapor (WVTR of 6 ± 1 g/m²·day) barriers at 50% relative humidity. It was also effective against oil penetration. Oxygen permeability was controlled by the presence of tight networks of cellulose and chitin nanofibers, while water vapor diffusion through the assembly was regulated by the continuous wax layer. Lastly, we showcased our fully renewable packaging material for preservation of the texture of a commercial cracker (dry food). Our material showed functionality similar to that of the original packaging, which was composed of synthetic polymers.