Lewis acid-promoted cascade reaction for the synthesis of Michael acceptors and its application in a dimerization reaction

Zhao, Xiao-Jing; Zhao, Jie; Sun, Xin; Liu, Ji-Kai; Wu, Bin

Lewis acid-promoted cascade reaction for the synthesis of Michael acceptors and its application in a dimerization reaction

2017

Zhao, Xiao-Jing | Zhao, Jie | Sun, Xin | Liu, Ji-Kai | Wu, Bin

An efficient Lewis acid-promoted cascade reaction with dimethyl sulfoxide as a methylene source for the synthesis of Michael acceptors is reported. The key to developing this procedure is the selection of a mild base to modulate the equilibrium of various intermediates in order to drive the reaction forward to the formation of Michael acceptor and dimeric compound products. Extensive studies were performed to gain insight into a possible reaction mechanism.

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AGROVOC Keywords

chemical structure

Bibliographic information

Published in

Tetrahedron

ISSN 0040-4020

Publisher

Elsevier Ltd

Other Subjects

Pummerer; Dimethyl sulfoxide; Dimethyl sulfoxide; Lewis acid; Dimerization; Dimerization; Michael acceptors

Language

English

Note

Pre-press version

License

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Type

Journal Article; Text

In AGRIS since: 2024-02-27

Format: MODS

Data Provider

This bibliographic record has been provided by National Agricultural Library

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Links

DOI http://dx.doi.org/10.1016/j.tet.2017.05.017

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