The kinetics of water uptake by food powders (animal and vegetable proteins and starch materials) were studied, and a mathematical relationship developed to describe the results. The water uptake rate was found to be proportional to the square of the amount of water still needing to be absorbed to reach equilibrium. The amount of water uptake was a function of the total water uptake at equilibrium and the time required to absorb half of the total uptake. A specific rate constant for the uptake was determined. (wz)

A starchy food that is initially a single-phase body turns into a multiphase body during boiling because of starch gelatinization. Fick's law is applicable only to a homogeneous system and is not applicable to such a multiphase system. Relative Water Content (RWC) model has been proposed as an alternative model that is able to describe water migration in multiphase food systems. In the RWC model, water migration is driven by the gradient of water content divided by the water holding capacity (WHC), m/m*. In this study a WHC profile (WHC plotted against water content with which starchy food is heat-treated) was assumed based on information concerning starch gelatinization. Using this WHC profile, the correlation between WHC profile and transient water content profile in a wheat flour dough slab during boiling was examined. A modified WHC profile was found to be applicable for describing certain characteristic features of the transient water content profile in a slab of wheat flour dough during boiling.

Water in oil emulsions would be prepared by silicones (SO), modified silicones (DC8500) and a food-grade stabilizer (starch 1). With increasing water contents, the emulsions turned from a liquid-like to gel-like behaviors with enhancing storage and loss modulus. When DC8500/SO was 1/17 with 10 wt% starch 1, a high internal phase emulsion can be obtained with 95 wt% water content. DC8500 and SO worked as efficient emulsifiers and possessed amphiphilic property to form emulsions with water in different ratios. A food-grade starch 1 was supplied as a stabilizer which can enhance both water content and strength of emulsion when added in a low concentration. Besides, it is indicated that the food-grade starches provided potential benefit on stabilizing emulsions in very low concentration.

Zein, corn prolamine, was dissolved in several organic solvents to make films and their properties were examined. Ethanol with 20% water and acetone with 30% water were found to dissolve zein well and transform it into a transparent flexible film after moderate drying. Both films showed similar breaking strength to that of commercial thin film of polyvinylidene chloride for food use and were digested with proteases. Only the film prepared from acetone solution showed a relatively low water permeability. This water permeation was found to depend strongly on the rate of diffusion. 1,2-Epoxy-3-chloropropane (ECP) was added into the acetone solution to cross-link the zein molecules for the purpose of improving the breaking strength and water-resistant properties of the film. Alpha-chymotrypsin was found to digest the film even after the modification with ECP. However, this cross-linking resulted in little improvement in the water-resistant properties of the film and also reduced its flexibility.

This work studied the structural changes and the migration of triacetin plasticizer in starch acetate films in the presence of distilled water as food simulant. Fourier-transform infrared spectroscopy result showed that the macromolecular interaction was enhanced to form compact aggregation of amorphous chains. The characterization of aggregation structures via wide and small angle X-ray scattering techniques indicated that the orderly microregion was compressed and the crystallites inside were “squeezed” to form interference and further aggregation. The compact aggregation structures restricted the mobility of macromolecules, triacetin and water molecules. The overall kinetic and the diffusion model analysis manifested that Fick's second law was the predominant mechanism for the short-term migration of triacetin. The increasing relaxation within film matrix caused the subsequent migration to deviate from Fick's law. The safe and reasonable application of the starch-based materials with restrained plasticizer migration could be accomplished by controlling the molecular interaction and aggregation structures.

A novel composite foam was prepared from native cassava starch and water hyacinth (WH) by baking in a hot mold. The effects of WH powder content (0, 3, 5, 7 or 10 wt%, dry starch basis) on the properties of the starch foam were investigated. A starch foam formulation with 5 wt% WH powder exhibited the highest flexural stress at maximum load (3.42 MPa), the highest flexural strain (extension) at maximum load (3.52%), the highest modulus (232.00 MPa), the lowest moisture content (6.77%) and the most uniform cell size distribution (0.44 ± 0.09 mm). Moreover, mechanical properties of starch foam with 5 wt% WH powder were better than the same properties of some commercial foams. After being coated with beeswax, the starch foams retained their shape after immersion in distilled water and their water solubility was significantly reduced. Results indicated that a starch foam/5 wt% WH composite with beeswax coating was a biodegradable foam that could possibly replace commercial non-degradable foam.

This work demonstrates the properties of calcium-fortified potato starch prepared by immersion in natural mineral water containing an extremely high level of calcium (468 ppm) and its food application. The calcium content of the fortified potato starch produced by use of the original mineral water was as high as 813 ppm, while calcium content of the control potato starch was 99 ppm. Rapid visco-analyzer data revealed that the calcium-fortified potato starch had a markedly lower peak viscosity and breakdown and a higher peak viscosity temperature than the control potato starch. Furthermore, calcium fortification caused a significant decrease in starch swelling power. Pound cakes made from the calcium-fortified potato starch and wheat flour blends tended to have a higher specific volume and sensory score of appearance than those made from the control potato starch and wheat flour blends. These findings suggest that the use of calcium-fortified potato starch is critical for making pound cakes with good quality in appearance.